The TCLP Question

Jun 9, 2014, 09:06 AM
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This new test, required of all waste shipped for disposal, could have serious consequences for the scrap recycling industry. Here are the basics of what you need to know about it.

There's no simple answer, but indications are that some materials that passed the predecessor test--the Extraction Procedure (EP) Toxicity test--may not pass the TCLP, and thus will be subject to federal hazardous waste regulations. (Toxicity is one of four characteristics that can designate a waste as hazardous under the Resource Conservation and Recovery Act.

Some scrap processors have found the new procedure to be more aggressive in leaching heavy metals, especially lead and cadmium, than the old EP Toxicity test. There is no grandfather clause for test results obtained with the EP Toxicity test.

Examining the Test

To whom does the TCLP apply?

The procedure must be performed on all waste (including recycling residues) shipped for disposal. The rule requiring the new test went into effect on Sept. 25 for all operations that generate more than 2,200 pounds of hazardous waste per month. Generators of between 220 and 2,200 pounds of hazardous waste per month have until March 29, 1991, to comply.

In essence, the test, like its predecessor, is designed to evaluate whether a waste is likely to leach one or more of a list of regulated constituents. However, the TCLP varies from the EP Toxicity test in a number of ways.

Regulated Constituents. The EP Toxicity test required evaluation for 14 constituents (including 8 heavy metals and 6 pesticides). The new test adds 26 organic chemicals to the list of regulated constituents, including benzene, which is commonly found in oil. Therefore, used oil, oily rags, oil filters, and other materials that may be contaminated with oils may be found hazardous under the TCLP.

Extraction Fluids. Under the TCLP there are two possible extraction fluids, the choice of which is based upon the relative acidity (pH) of the waste. Extract No. 1, to be used on wastes with relatively low pH levels, is essentially the same extraction fluid required under the old procedure. However, because of other differences in the two tests, the fluid actually produces a consistently more acidic leaching solution. Wastes containing sufficient alkaline compounds or those with naturally occurring high pH levels would require use of Extract No. 2, a more acidic leaching fluid.

Extraction Time. The extraction time is 18 hours for the TCLP and 24 hours for the EP Toxicity test.

Filter Size. The TCLP requires use of a 0.6 to 0.8 micron filter opening while the EP Toxicity method uses a prefilter followed by a 0.45 micron final filter. While the size of the filter in both is extremely small, the larger opening and the deletion of the prefilter in the TCLP requirements could affect the test results.

Dealing With Failure

What do you do if your waste material doesn't pass the TCLP?

Persons who generate wastes that are found hazardous under the TCLP must immediately notify their regional office of the U. S. Environmental Protection Agency (EPA) and obtain an EPA Identification Number. Both of these requirements may be satisfied by completing EPA Form 8700-12.

Companies that already have submitted notification of their status as hazardous waste generators and have a hazardous waste generator number are not required to provide additional notification. However, those that generate hazardous waste at more than one location must submit a separate form for each location. Note that under RCRA, fin-ns that fail to file are subject to fines as high as $25,000 per day.

If you store, treat, or dispose of hazardous waste on-site you will likely be required to file a two-part permit application with the EPA. Part A of the application must be submitted immediately. You have until September 1991 to submit Part B, which requests detailed facility information (including waste analysis; monitoring and inspection; closure and post-closure care; recordkeeping; requirements for ignitable, reactive, and incompatible wastes; and general operating requirements).

Permitted facilities are inspected periodically. If operations have been altered or if there is a compliance problem, the EPA may modify the conditions of the permit or revoke and reissue it. Furthermore, the permit can be terminated if the facility is not in compliance with the terms of the permit, if the permit holder fails to disclose relevant information, or if it is determined that the permitted activity endangers human health or the environment and can only be regulated to acceptable levels by permit termination.

If you ship the hazardous waste off-site, you must use only authorized hazardous waste transporters with EPA identification numbers. In addition, all containers must be packaged and labeled in accordance with U.S. Department of Transportation regulations (contact the department at 202/366-5580 or your state's transportation agency for assistance). Furthermore, all shipments must be accompanied by a Uniform Hazardous Waste Manifest (EPA Form 8700-22). Finally, you, as the generator, may only send the wastes to a facility that is permitted, licensed, or authorized by the EPA or the state to accept hazardous waste. Hazardous waste generators are legally responsible for their wastes at all times.

Expanding Regulatory Concerns

What other federal programs that scrap recyclers might be subject to will the TCLP affect?

Land Disposal Restrictions Program. Most hazardous wastes are prohibited from land disposal, unless treated to levels established by the Land Disposal Restrictions (LDR) program. However, wastes that tested nonhazardous under the EP Toxicity test, even if they now test hazardous under the TCLP, are exempt from the treatment requirements specified in the LDR program. All other hazardous waste requirements under RCRA still apply.

CERCLA. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), more commonly known as Superfund, is aimed at cleaning up toxic releases at uncontrolled or abandoned hazardous waste sites. If the soil and debris generated during Superfund cleanup activities fail the TCLP, they must be handled as hazardous wastes. In addition, the new constituents regulated under the TCLP have been added to the CERCLA list of hazardous substances.

Underground Storage Tanks. EPA has deferred from regulation under Subtitle C--the hazardous waste provisions of RCRA--petroleum-contaminated soils and debris generated from collective action activities at leaking underground storage tank sites. However, the deferral does not apply to tank bottom material associated with cleaning and removal, nor does it apply to nonregulated tanks such as heating oil tanks and above-ground tanks.

Obtaining Help

What can scrap recyclers do to reduce the chance of their residues being considered hazardous?

Some members of the industry have been able to lower the concentration of heavy metals in their wastes through improved source control measures. By inspecting for and removing multiple mufflers, batteries, gas tanks, cable ends, and trash from inbound scrap, many recyclers have been able to easily and consistently pass the TCLP.

It also may be helpful to consult a technical expert to ensure that samples are being properly prepared and tested.

If you are uncertain as to whether your company produces hazardous waste or if you need additional information, contact an environmental consultant, your EPA regional office, the EPA's RCRA/Superfund Hotline (800/424-9346), or your state hazardous waste management agency.

[SIDEBAR]

What Is Hazardous Waste?

Determining whether a waste is hazardous under Subtitle C (the hazardous waste section of RCRA) is fairly complex. There are, however, a few principles that guide the law’s definition.

First, in order for a waste to be defined as hazardous, it must be a “solid waste.” Solid waste is defined by the EPA as “discarded material,” and can be in solid, semi-solid, or liquid form. Discarded materials include any materials that are:

Abandoned by being disposed of, burned, or incinerated or

Recycled in one of the following ways: application to land in a manner constituting disposal, burning for energy recovery, reclamation (that is, processed to recover a usable product), or speculative accumulation (which applies when less than 75 percent of a material accumulated on-site is not recycled during a calendar year).

Thus, scrap that is reclaimed or stored prior to reclamation is considered a solid waste. Drosses, slags, sweat furnace ash, and other smelting or refining residues are defined as “byproducts” by the EPA. Under RCRA, byproducts are defined as solid wastes if speculatively accumulated or abandoned; however, they are not solid wastes (and thus not hazardous wastes) if reclaimed.

Next, a solid waste is considered by the EPA to be a hazardous waste if either of the following is true:

It exhibits any one of the characteristics of a hazardous waste: ignitability, corrosivity, reactivity, or toxicity (toxicity is the most common characteristic present in scrap processing residues).

It has been specifically listed by the agency in Subpart D of 40 CFR Part 261 as a hazardous waste.

A mixture containing a listed hazardous waste and a nonhazardous solid waste also is usually considered a hazardous waste. In addition, any solid waste derived from the treatment, storage, or disposal of a listed hazardous waste is considered a hazardous waste. This could include spill residues, ash, emission control dust, and leachate.

The law requires every generator of solid waste to determine whether its waste is hazardous. Testing is required unless the generator has some other basis for deciding that the waste is or is not hazardous.

[SIDEBAR]

Constituents Regulated Under the TCLP

Old EP Toxicity Regulated Constituents:

Arsenic, barium, cadmium, chromium, 2,4-D, endrin, lead, lindane, mercury, methoxychlor, selenium, silver, toxaphene, 2,4,5-TP (silvex)

 Organic Constituents Added by the TCLP:

This new test, required of all waste shipped for disposal, could have serious consequences for the scrap recycling industry. Here are the basics of what you need to know about it.

There's no simple answer, but indications are that some materials that passed the predecessor test--the Extraction Procedure (EP) Toxicity test--may not pass the TCLP, and thus will be subject to federal hazardous waste regulations. (Toxicity is one of four characteristics that can designate a waste as hazardous under the Resource Conservation and Recovery Act.

Some scrap processors have found the new procedure to be more aggressive in leaching heavy metals, especially lead and cadmium, than the old EP Toxicity test. There is no grandfather clause for test results obtained with the EP Toxicity test.

Examining the Test

To whom does the TCLP apply?

The procedure must be performed on all waste (including recycling residues) shipped for disposal. The rule requiring the new test went into effect on Sept. 25 for all operations that generate more than 2,200 pounds of hazardous waste per month. Generators of between 220 and 2,200 pounds of hazardous waste per month have until March 29, 1991, to comply.

In essence, the test, like its predecessor, is designed to evaluate whether a waste is likely to leach one or more of a list of regulated constituents. However, the TCLP varies from the EP Toxicity test in a number of ways.

Regulated Constituents. The EP Toxicity test required evaluation for 14 constituents (including 8 heavy metals and 6 pesticides). The new test adds 26 organic chemicals to the list of regulated constituents, including benzene, which is commonly found in oil. Therefore, used oil, oily rags, oil filters, and other materials that may be contaminated with oils may be found hazardous under the TCLP.

Extraction Fluids. Under the TCLP there are two possible extraction fluids, the choice of which is based upon the relative acidity (pH) of the waste. Extract No. 1, to be used on wastes with relatively low pH levels, is essentially the same extraction fluid required under the old procedure. However, because of other differences in the two tests, the fluid actually produces a consistently more acidic leaching solution. Wastes containing sufficient alkaline compounds or those with naturally occurring high pH levels would require use of Extract No. 2, a more acidic leaching fluid.

Extraction Time. The extraction time is 18 hours for the TCLP and 24 hours for the EP Toxicity test.

Filter Size. The TCLP requires use of a 0.6 to 0.8 micron filter opening while the EP Toxicity method uses a prefilter followed by a 0.45 micron final filter. While the size of the filter in both is extremely small, the larger opening and the deletion of the prefilter in the TCLP requirements could affect the test results.

Dealing With Failure

What do you do if your waste material doesn't pass the TCLP?

Persons who generate wastes that are found hazardous under the TCLP must immediately notify their regional office of the U. S. Environmental Protection Agency (EPA) and obtain an EPA Identification Number. Both of these requirements may be satisfied by completing EPA Form 8700-12.

Companies that already have submitted notification of their status as hazardous waste generators and have a hazardous waste generator number are not required to provide additional notification. However, those that generate hazardous waste at more than one location must submit a separate form for each location. Note that under RCRA, fin-ns that fail to file are subject to fines as high as $25,000 per day.

If you store, treat, or dispose of hazardous waste on-site you will likely be required to file a two-part permit application with the EPA. Part A of the application must be submitted immediately. You have until September 1991 to submit Part B, which requests detailed facility information (including waste analysis; monitoring and inspection; closure and post-closure care; recordkeeping; requirements for ignitable, reactive, and incompatible wastes; and general operating requirements).

Permitted facilities are inspected periodically. If operations have been altered or if there is a compliance problem, the EPA may modify the conditions of the permit or revoke and reissue it. Furthermore, the permit can be terminated if the facility is not in compliance with the terms of the permit, if the permit holder fails to disclose relevant information, or if it is determined that the permitted activity endangers human health or the environment and can only be regulated to acceptable levels by permit termination.

If you ship the hazardous waste off-site, you must use only authorized hazardous waste transporters with EPA identification numbers. In addition, all containers must be packaged and labeled in accordance with U.S. Department of Transportation regulations (contact the department at 202/366-5580 or your state's transportation agency for assistance). Furthermore, all shipments must be accompanied by a Uniform Hazardous Waste Manifest (EPA Form 8700-22). Finally, you, as the generator, may only send the wastes to a facility that is permitted, licensed, or authorized by the EPA or the state to accept hazardous waste. Hazardous waste generators are legally responsible for their wastes at all times.

Expanding Regulatory Concerns

What other federal programs that scrap recyclers might be subject to will the TCLP affect?

Land Disposal Restrictions Program. Most hazardous wastes are prohibited from land disposal, unless treated to levels established by the Land Disposal Restrictions (LDR) program. However, wastes that tested nonhazardous under the EP Toxicity test, even if they now test hazardous under the TCLP, are exempt from the treatment requirements specified in the LDR program. All other hazardous waste requirements under RCRA still apply.

CERCLA. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), more commonly known as Superfund, is aimed at cleaning up toxic releases at uncontrolled or abandoned hazardous waste sites. If the soil and debris generated during Superfund cleanup activities fail the TCLP, they must be handled as hazardous wastes. In addition, the new constituents regulated under the TCLP have been added to the CERCLA list of hazardous substances.

Underground Storage Tanks. EPA has deferred from regulation under Subtitle C--the hazardous waste provisions of RCRA--petroleum-contaminated soils and debris generated from collective action activities at leaking underground storage tank sites. However, the deferral does not apply to tank bottom material associated with cleaning and removal, nor does it apply to nonregulated tanks such as heating oil tanks and above-ground tanks.

Obtaining Help

What can scrap recyclers do to reduce the chance of their residues being considered hazardous?

Some members of the industry have been able to lower the concentration of heavy metals in their wastes through improved source control measures. By inspecting for and removing multiple mufflers, batteries, gas tanks, cable ends, and trash from inbound scrap, many recyclers have been able to easily and consistently pass the TCLP.

It also may be helpful to consult a technical expert to ensure that samples are being properly prepared and tested.

If you are uncertain as to whether your company produces hazardous waste or if you need additional information, contact an environmental consultant, your EPA regional office, the EPA's RCRA/Superfund Hotline (800/424-9346), or your state hazardous waste management agency.

[SIDEBAR]

What Is Hazardous Waste?

Determining whether a waste is hazardous under Subtitle C (the hazardous waste section of RCRA) is fairly complex. There are, however, a few principles that guide the law’s definition.

First, in order for a waste to be defined as hazardous, it must be a “solid waste.” Solid waste is defined by the EPA as “discarded material,” and can be in solid, semi-solid, or liquid form. Discarded materials include any materials that are:

Abandoned by being disposed of, burned, or incinerated or

Recycled in one of the following ways: application to land in a manner constituting disposal, burning for energy recovery, reclamation (that is, processed to recover a usable product), or speculative accumulation (which applies when less than 75 percent of a material accumulated on-site is not recycled during a calendar year).

Thus, scrap that is reclaimed or stored prior to reclamation is considered a solid waste. Drosses, slags, sweat furnace ash, and other smelting or refining residues are defined as “byproducts” by the EPA. Under RCRA, byproducts are defined as solid wastes if speculatively accumulated or abandoned; however, they are not solid wastes (and thus not hazardous wastes) if reclaimed.

Next, a solid waste is considered by the EPA to be a hazardous waste if either of the following is true:

It exhibits any one of the characteristics of a hazardous waste: ignitability, corrosivity, reactivity, or toxicity (toxicity is the most common characteristic present in scrap processing residues).

It has been specifically listed by the agency in Subpart D of 40 CFR Part 261 as a hazardous waste.

A mixture containing a listed hazardous waste and a nonhazardous solid waste also is usually considered a hazardous waste. In addition, any solid waste derived from the treatment, storage, or disposal of a listed hazardous waste is considered a hazardous waste. This could include spill residues, ash, emission control dust, and leachate.

The law requires every generator of solid waste to determine whether its waste is hazardous. Testing is required unless the generator has some other basis for deciding that the waste is or is not hazardous.

[SIDEBAR]

Constituents Regulated Under the TCLP

Old EP Toxicity Regulated Constituents:

Arsenic, barium, cadmium, chromium, 2,4-D, endrin, lead, lindane, mercury, methoxychlor, selenium, silver, toxaphene, 2,4,5-TP (silvex)

 Organic Constituents Added by the TCLP:

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